https://doi.org/10.1051/epjap/2021210101
Regular Article
Effect of vacuum annealing on the properties of one step thermally evaporated Sb2S3 thin films for photovoltaic applications
1
Université de Tunis El Manar, Ecole National d’Ingénieurs de Tunis, Laboratoire de Photovoltaïque et Matériaux Semi-conducteurs 1002, Tunisia
2
Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB 08193 Bellaterra, Spain
3
Université de Tunis, IPEITunis Montfleury, Laboratoire de Photovoltaïques et Matériaux Semi-conducteurs-ENIT, Tunisia
* e-mail: emnagnenna@gmail.com
Received:
27
April
2021
Received in final form:
17
September
2021
Accepted:
4
October
2021
Published online: 26 October 2021
Sb2S3 films were deposited on unheated glass substrates by thermal evaporation and annealed under vacuum atmosphere for 2 hours at different temperatures. Different characterization techniques were used to better understand the behavior of the Sb2S3 material. XRD and Raman spectroscopy confirmed the formation of pure Sb2S3 powder with orthorhombic lattices. The effect of vacuum annealing on the properties of the films was studied. XRD analysis revealed that as-deposited and annealed films at 150 °C were amorphous in nature whereas those annealed at T ≥ 200 °C were polycrystalline. The crystallite size of the films showed a decrease from 75.8 to 62.9 nm with the increase of the annealing temperature from 200 to 250 °C. The Raman showed several peaks corresponding to the stibnite Sb2S3 phase. The surface morphology of the films was examined by AFM. The roughness decreases slightly as the transformation from the amorphous to the crystalline phase occurs. The chemical compositions of Sb2S3 films were analyzed by EDS, revealing that all films were Sb-rich. The optical parameters were estimated from the transmittance and reflectance spectra recorded by UV-Vis spectroscopy. A reduction in the band gap energy from 2.12 to 1.70 eV with the increase of annealing temperature was also found.
© EDP Sciences, 2021
